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Synthesis and characterization of cerium (III) and (IV) compounds
(University of Missouri--Columbia, 2022)
Treatment of Cp*2CeCl2K with various aryl alcohols and amines produces Cp*2Ce(O- 2,6-iPr2C6H3) and Cp*2Ce(N(C6H5)2). The crystallographic structures are presented as well as their fluorescence. Absorbance measurements ...
Advancing Uranium(III) reductive chemistry through hetroleptic metallocene aryloxide ligand frameworks
(University of Missouri--Columbia, 2023)
This dissertation looks at the reductive chemistry of Uranium (III)bis- pentamethylcyclopentadienyl arylox-ide complexes. For chapter two, the reactivity of two metallocene aryloxide U(III) complexes, [(C5Me5)2U(O-Ar)], R ...